Dihydrogen monoxide 

"Dihydrogen monoxide" redirects here. For the H2O molecule, see Water (molecule).
Water is made from two hydrogen and one oxygen atom, giving the name dihydrogen monoxide.

The dihydrogen monoxide hoax involves listing negative effects of water under an unfamiliar scientific name, then asking individuals to help control the seemingly dangerous substance. The hoax is designed to illustrate how the lack of scientific knowledge and an exaggerated analysis can lead to misplaced fears.1 Dihydrogen monoxide, shortened to DHMO, is a scientific name for water that, while technically correct, is almost never employed.

The hoax was created by Eric Lechner, Lars Norpchen and Matthew Kaufman, housemates while attending UC Santa Cruz in 1990,2 revised by Craig Jackson in 1994,3 and brought to widespread public attention in 1997 when Nathan Zohner, a 14-year-old student, gathered petitions to ban "DHMO" as the basis of his science project, titled "How Gullible Are We?"4

Contents

Terminology

"Dihydrogen Monoxide" in its liquid form

"Dihydrogen monoxide" may sound dangerous to those with a limited knowledge of chemistry or who hold to an ideal of a "chemical-free" life.4 The only familiar common usage of the term "monoxide" is in the highly poisonous gas "carbon monoxide", and the simplified term "monoxide poisoning" is commonly used to refer to poisoning by this colorless and odorless substance.5 Health officials frequently advise the purchase and usage of carbon monoxide detectors to protect against this poison, which is itself sometimes referred to simply as "monoxide".

The water molecule has the chemical formula H2O, meaning each molecule of water is composed of two hydrogen atoms and one oxygen atom. Literally, the term "dihydrogen monoxide" means "two hydrogen, one oxygen", consistent with its molecular formula: the prefix di- in dihydrogen means "two", the prefix mono- in monoxide means "one", and an oxide is a compound that contains one or more oxygen atoms.6

The use of numerical prefixes is typical nomenclature for compounds formed by covalent bonds, which are present in water.78 The prefix for the first named element is often dropped if the elements involved commonly form only one compound, or even if the number of atoms of the first-named element is the same in all the compounds of the two (or more) elements.6 Thus H2S is often simply called hydrogen sulfide, and lithium oxide is a common name for Li2O. However, the names dihydrogen sulfide,9 dilithium oxide,10 and dilithium monoxide11 are also commonly used both in industry and in universities.

The mono- prefix is often dropped for the second-named element if it is the only common compound the elements form.12 Thus for instance the IUPAC name of H2S is hydrogen sulfide rather than hydrogen monosulfide.13 However, since carbon and oxygen can form several compounds (carbon monoxide, carbon dioxide, tricarbon dioxide, and dicarbon monoxide), the mono- prefix is kept, as it is with silicon monoxide and silicon dioxide. Indeed, hydrogen and oxygen do form another common compound, H2O2. (Using prefix nomenclature, H2O2 would be called dihydrogen dioxide—also known as hydrogen peroxide.) Thus, keeping the mono- in dihydrogen monoxide does serve to distinguish it from another compound.

Water has a regular scientific or systematic name of hydrogen oxide, as well as an alkali name of hydrogen hydroxide and several acid names such as hydroxic acid, hydroxylic acid, and hydroxilic acid. Incidentally, the term "hydroxyl acid" used in the original hoax is slightly incorrect, as it does not follow convention. Additional names of μ-oxido dihydrogen and oxidane have been developed for this compound.

Under the 2005 revisions of IUPAC nomenclature of inorganic chemistry, there is no single correct name for every compound.14 The primary function of chemical nomenclature is to ensure that the person who hears or reads a chemical name is under no ambiguity as to which chemical compound it refers: each name should refer to a single substance. It is considered less important to ensure that each substance should have a single name, although the number of acceptable names is limited.14 Water is one acceptable name for this compound, even though it is neither a systematic nor international name, and is specific to one phase of the compound. The other IUPAC recommendation is oxidane.15

Original web appearance

The first appearance on the web was attributed by the Pittsburgh Post-Gazette to the so-called Coalition to Ban Dihydrogen Monoxide,163 a hoax organization started by Craig Jackson following the initial newsgroup discussions. The site included the following "warning":17

Dihydrogen monoxide:

Despite the danger, dihydrogen monoxide is often used:

The original webpage is no longer accessible, but a October 31, 1996 version has been mirrored by The Internet Archive.18

Public efforts involving DHMO

The logo of DHMO.org, primary current residence of the dihydrogen monoxide hoax

See also

References

  1. ^ a b Carder, L; Willingham, P.; Bibb, D. (2001), "Case-based, problem-based learning: Information literacy for the real world", Research Strategies 18: 181-190, http://linkinghub.elsevier.com/retrieve/pii/S0734331002000873 .
  2. ^ Erich Lechner (1990), Warning! Dangerous Contamination! (original usenet posting), Usenet rec.humor.funny archive (published February 23, 1990), http://groups.google.com/group/rec.humor.funny/browse_thread/thread/3f985a069a2a19d8/ 
  3. ^ a b Kruszelnicki, Karl S. (2006), Mysterious Killer Chemical, Australian Broadcasting Corporation, http://www.abc.net.au/science/k2/moments/s1631494.htm .
  4. ^ a b c d Dihydrogen Monoxide from Urban Legends Reference Pages, accessed 25 September 2006.
  5. ^ Knight, Bernard (1998). Lawyers Guide to Forensic Medicine, Routledge. pp.280. ISBN 9781859411599, http://books.google.ca/books?id=CMA4_NHHc8wC&pg=PA63&lpg=PA63&dq=%22monoxide+poisoning%22+-carbon&source=bl&ots=MiliDmC5j5&sig=uOucClGH-2FD9sdMaFUvPEcRi6k&hl=en&sa=X&oi=book_result&resnum=2&ct=result. 
  6. ^ a b Van Bramer, S.E. (1996), Chemical Nomenclature, http://science.widener.edu/svb/pset/nomen_b.html .
  7. ^ Leigh, G. J. et al. 1998. Principles of chemical nomenclature: a guide to IUPAC recommendations, p. 28. Blackwell Science Ltd, UK. ISBN 0-86542-685-6.
  8. ^ Nishiura, James, "Polar Covalent Bonds", Biology 4, City University of New York, http://academic.brooklyn.cuny.edu/biology/bio4fv/page/polar_c.htm .
  9. ^ Office of Environmental Health Hazard Assessment, Dihydrogen sulfide, California Environmental Protection Agency, http://www.oehha.ca.gov/air/chronic_rels/pdf/7783064.pdf .
  10. ^ Diagnostics on calculations: Species with negative natural orbital occupation numbers, National Institutes of Health, http://cccbdb.nist.gov/diagnostics.asp 
  11. ^ Lithium oxide, PubChem public chemical database, http://pubchem.ncbi.nlm.nih.gov/summary/summary.cgi?cid=82891&loc=ec_rcs 
  12. ^ Leigh, G. J. et al. 1998. Principles of chemical nomenclature: a guide to IUPAC recommendations, p. 28. Blackwell Science Ltd, UK. ISBN 0-86542-685-6: "The multiplicative prefixes may not be necessary if the oxidation states are explicit or are clearly understood."
  13. ^ Hydrogen sulfide, PubChem public chemical database, http://pubchem.ncbi.nlm.nih.gov/summary/summary.cgi?cid=402 .
  14. ^ a b IUPAC Report: General Aims, Functions and Methods of Chemical Nomenclature (March 2004) http://www.iupac.org/reports/provisional/abstract04/RB-prs310804/Chap1-3.04.pdf
  15. ^ Leigh, G. J. et al. 1998. Principles of chemical nomenclature: a guide to IUPAC recommendations, p. 99. Blackwell Science Ltd, UK. ISBN 0-86542-685-6
  16. ^ Roddy., Dennis B. (1997), Internet-inspired prank lands 4 teens in hot water, Pittsburgh Post-Gazette (published April 19, 1997) 
  17. ^ a b Craig Jackson (1994), Ban Dihydrogen Monoxide!, Coalition to ban DHMO, http://web.archive.org/web/19961031232918/http://media.circus.com/~no_dhmo/ . Coalition to ban DHMO officers, Coalition to ban DHMO, http://web.archive.org/web/19970125144038/media.circus.com/~no_dhmo/members.html .
  18. ^ "Ban Dihydrogen Monoxide!".
  19. ^ The original poster circulated at UC Santa Cruz (PDF)
  20. ^ http://www.armory.com/~crisper/DHMO/
  21. ^ Glassman, James K (1997). "Dihydrogen Monoxide: Unrecognized Killer", The Washington Post. Retrieved on 8 March 2007. 
  22. ^ Campaign launched against dihydrogen monoxide, Deutsche Presse-Agentur, 1998 (published April 1, 1998) .
  23. ^ a b Gnad, Megan (2007-09-14). "MP tries to ban water". New Zealand Herald.
  24. ^ "Penn & Teller: Bullshit!" Environmental Hysteria (2003), Internet Movie Database, http://www.imdb.com/title/tt0672528/ 
  25. ^ Local officials nearly fall for H2O hoax, at MSNBC 15 March 2004, accessed 25 September 2006.
  26. ^ Water without hydrogen would warrant warning, Louisville Courier-Journal, Monday, July 17, 2006 (link inactive as of Friday, May 18, 2007)
  27. ^ Danger! H in H2O, Chemical & Engineering News, October 23, 2006 webcite mirror
  28. ^ Number10.gov.uk - Petitions - Search Results
  29. ^ "Questions And Answers - Wednesday, 12 September 07". Scoop (2007-09-13).
  30. ^ "PDF file of related correspondence". Scoop (2007-09-13).

External links